Frontispiece: Alkynyl Coinage Metal Clusters and Complexes-Syntheses, Structures, and Strategies
نویسندگان
چکیده
منابع مشابه
Alkynyl-functionalized gold NHC complexes and their coinage metal clusters.
Phenylpropynyl-functionalized imidazolium salts, as well as their gold complexes, were prepared in excellent yields affording suitable starting materials for metal cluster synthesis. The reactions of these gold complexes with coinage metal phenylacetylides [M(CCPh)](x) (M = Cu, Ag) resulted in the formation of novel heterometallic hexanuclear clusters which exhibit mixed metallophillic interact...
متن کاملCorrection: Alkynyl-functionalized gold NHC complexes and their coinage metal clusters.
The authors regret that the incorrect CCDC numbers have been quoted in the footnote referencing the Electronic Supplementary Information (ESI) on the first page of the above article. The correct ESI footnote is shown below with CCDC numbers 1059550–1059555 as quoted in the Acknowledgments, and not 1040816–1040823. The CIF files posted originally were also incorrect. These were replaced with the...
متن کاملExperimental and computational studies of alkali-metal coinage-metal clusters.
Coinage and alkali metal mixed clusters, M4Na- (M = Cu, Au) have been investigated experimentally using photoelectron spectroscopy and computationally at correlated ab initio levels. The related Cu4Li-, Ag4Li-, Ag4Na-, and Au4Li- clusters as well as the neutral Cu4Li2 and Cu4Na2 clusters have also been studied computationally. The calculations show that the two lowest isomers of the negatively ...
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Terminal arylalumylene complexes of platinum [Ar-Al-Pt(PCy3 )2 ] (Ar=2,6-[CH(SiMe3 )2 ]2 C6 H3 (Bbp) or 2,6-[CH(SiMe3 )2 ]2 -4-(tBu)C6 H2 (Tbb)) have been synthesized either by the reaction of a dialumene-benzene adduct with [Pt(PCy3 )2 ], or by the reduction of 1,2-dibromodialumanes Ar(Br)Al-Al(Br)Ar in the presence of [Pt(PCy3 )2 ]. X-Ray crystallographic analysis reveals that the AlPt bond ...
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ژورنال
عنوان ژورنال: Chemistry - A European Journal
سال: 2018
ISSN: 0947-6539
DOI: 10.1002/chem.201883061